Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane.
نویسندگان
چکیده
Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when iPr-Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one-pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.
منابع مشابه
Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 54 43 شماره
صفحات -
تاریخ انتشار 2015